Special CMP Seminar Thursday, March 7, 2002 11:30 am, Room 224 Physics-Astronomy Building Gold Nanocrystal Arrays: Synthesis, Self-Assembly and Electronic Transport Xiao-Min Lin James Franck Institute University of Chicago Abstract Chemical synthesis of nanocrystals is one of the most efficient ways to create nano-size building blocks for future electronic devices. Kinetically controlled syntheses have been developed in the past decade to obtain monodispersed semiconductor and metallic nanocrystals. We have discovered an alternative digestive ripening process to synthesize monodispsed gold nanocrystals. Much like normal atoms, colloidal nanocrystals can form 3D superlattices due to long range van der Waals interaction. By controlling the dewetting of the solvent, highly long-range ordered nanocrystal monolayers and bilayers can also be formed on silicon nitride substrate. Lateral patterning of nanocrystals on the solid substrate can be achieved by combining the self-assembly process with standard electron beam lithography. These new techniques allow us to study the electronic transport through tunneling junction arrays at a length scale that has been impossible to achieve previously. Coulomb blockade of individual nanocrystals causes high voltage thresholds and nonlinear current voltage curve. Robust power law scaling behavior was observed in highly ordered nanocrystal arrays, while deviation from single power law was found in disordered arrays. These phenomena were attributed to both the charge disorder and the structural disorder. Curriculum Vitae: Fellow – University of Chicago-Argonne National Laboratory Consortium for Nanoscale Research. (2001-present) Postdoctoral Fellow - The James Franck Institute, The University of Chicago. (2000- 2001) Advisor: Prof. Heinrich M. Jaeger Ph.D. Condensed Matter Physics - Kansas State University (1999) Advisor: Prof. Christopher M. Sorensen M.S. Inorganic Chemistry - Kansas State University (1999) Advisor: Prof. Kenneth. J. Klabunde. M.S. Condensed Matter Physics - Shanghai JiaoTong University (1994) Advisor: Prof. Hong Sun B.S. Applied Physics (Major) - Shanghai JiaoTong University (1991) B.S. Telecommunication Engineering (Minor) - Shanghai JiaoTong University (1991)