Physics and Astronomy Colloquium Tuesday, February 5, 2002 4:10 p.m., Room 224 Physics-Astronomy Building (Dr. Larbalestier will meet with students in Room 224 from 3:15-3:45 p.m. on Tuesday) Refreshment served at 3:45 p.m. outside Room 224 ********************************************** MAGNESIUM DIBORIDE - A SURPRISING NEW SUPERCONDUCTOR David C Larbalestier University of Wisconsin-Madison Twelve months ago a surprising announcement was made that the "simple" compound MgB2 was superconducting at 39 K. It was very quickly established that a strong isotope effect occurred in the layered hexagonal compound and that it was an electron-phonon superconductor. However the material consists of Mg and B layers with significant charge transfer from the Mg to the B layer, leading to significant electronic anisotropy. My colleagues and I posed the question whether the material was weak linked and what the anisotropy might be. The answers that we developed were a.) that grain boundaries are not obstacles to current flow, as they sadly are in high-Tc materials (1), b.) that c-axis textured thin films have anisotropy of order two (2), and c.) that thin films can be alloyed with unknown elements - probably O - take MgB2 all the way to the dirty limit, maximizing Hc2 but also somewhat depressing Tc (3). These results, obtained by mid-2001 have generally stood the test of time, but various newer measurements are not always in agreement. It is now clear that "well-made" MgB2 can exhibit a variety of Tc values that range from below 20 K to 40 K. Anisotropy values range from 2 to more than 6 and it is now common to think that there are two gaps in the compound. So an apparently simple superconductor may not be so simple after all! A review of present knowledge of the material from my viewpoint of its potential for high critical current density and high field use will be made, situating my view in the context of the broader work being done on this surprising new superconductor (4). (1) D. C. Larbalestier, L. D. Cooley, M. O. Rikel, A. A. Polyanskii, J. Jiang, S. Patnaik, X. Y. Cai, D. M. Feldmann, A. Gurevich, A. A. Squitieri, M. T. Naus, C. B. Eom, E. E. Hellstrom, R. J. Cava, and K. A. Regan, "Strongly Linked Current Flow in Polycrystalline Forms of the Superconductor MgB2," Nature, 410: 186-189, 2001. (2) 1. C.B. Eom, M.K. Lee, J.H. Choi, L. J. Belenky, X. Song, L.D. Cooley, M.T. Naus, S. Patnaik, J. Jiang, M. Rikel, A. Polyanskii, A. Gurevich, X.Y. Cai, S.D. Bu, S.E. Babcock, E.E. Hellstrom, and D.C. Larbalestier, "Very High Critical Current Density and Enhanced Irreversibility Field in Magnesium Diboride Films", Nature 411: 558-560, 2001 (3) S. Patnaik, L.D. Cooley, A. Gurevich, A.A. Polyanskii, J.Y. Jiang, X.Y. Cai, A.A. Squitieri, M.T. Naus, M.K. Lee, J.H. Choi, L. Belenky, S.D. Bu, J. Letteri, X. Song, D.G. Schlom, S. E. Babcock, C. B. Eom E.E. Hellstrom and D. C. Larbalestier "Electronic Anisotropy, Magnetic Field-Temperature Phase Diagram and their Dependence on Resistivity in c-Axis Oriented MgB2 Thin Films", Superconductor Science and Technology 14, 315-319, (2001). (4) David Larbalestier, Alex Gurevich, Matthew Feldmann and Anatoly Polyanskii, "High Transition Temperature Superconducting Materials For Electric Power Applications", Nature 414, 368-377, (2001).