SCIENCE AT THE EDGE SEMINAR SERIES Interdisciplinary Physics Seminar Friday, 06 April 2012 at 11:30am Room 1400 Biomedical and Physical Sciences Bldg. Refreshments at 11:15 Speaker: Victor Karpov Department of Physics and Astronomy University of Toledo Title: Physics of Thin Film Photovoltaics Abstract: Thin film photovoltaics (PV), particularly based on CdTe and CIGS absorbers, are rapidly taking over world energy markets. But do we understand their operations? Is that the same old concept of illuminated p-n junction making it from one textbook to another or is there some new physics behind their success? As an introduction, I will give a brief 'first hand' account of a history of the First Solar LLC, the company that started thin film PV to become a world leader: its product, evolution, and current problems. The topic of physics per se will start with a short review of the mainstream understanding of classical photovoltaics (crystalline Si, etc.), showing that it is absolutely insufficient to understand thin film photovoltaics and yet is blindly applied. I will then introduce several qualitatively different concepts based on the experimental observations that form a new physics of thin-film PV. They include the concept of random diode arrays, piezo-photovoltaic coupling, and reach-through interactions. My talk will include some practical implications, particularly the "red wine effect" highlighted in the media. At the end, I will try to convey the message that physicists owe a lot to the fascinating field of thin film PV that keeps evolving by trial and error.